Introduction of Indium
INDIUM
Physical Properties of Indium Metal
Indium was first discovered in Germany in 1863 and became the 49th element in
Periodic Table.
The name indium relates to its indigo blue spectral lines. The metal is a
lustrous silver-white. It is very malleable and ductile and can be easily
formed. It remains soft to temperatures approaching absolute zero, making it
ideal for cryogenic and vacuum applications.
Some of the other characteristics of indium include:
1). Cold Welding: Oxide free indium has the unique ability to cold weld or attach to itself. Parts coated with indium can be bonded together without the addition of heat or chemicals.
2).Metal Catalyst: Doping other pure metals with small amounts of indium, results in alloys that can be stronger or harder. For example, one of the first applications of indium is its addition to dental alloys.
3).Improve Resistance to Thermal Fatigue: When indium is added to standard solder alloys, the joint is less likely to fail due to thermal fatigue.
4).Reduce Gold Scavenging:When soldering to gold or gold-plated surfaces, solder has a tendency to dissolve gold into the joint. The addition of indium to the solder will reduce this tendency.
5).Low Melting Point Alloys:Indium is often used to produce low melting point alloys which are used as fuses or temperature indicators. Low melting point alloys are also used in the optical industry to hold or "block" lenses during the polishing process. The polishing machine tool grip the alloy, not the lens, allowing the lens to be polished with minimized distortion. The alloy's low melting point then allows it to be removed from the lens with a minimum of heat and no damage.
6).Join Materials with Different CTE's: Many times, materials being joined have different coefficients of thermal expansion (CTE). Traditional solder joints can crack during the expansion/contraction process because of this. Indium, when added to a solder alloy, provides ductility which can enable the materials to expand and contract at their individual rates while absorbing the CTE difference of the other material, all without cracking the bond.
7).Bond Glass, Quartz and Ceramics:These materials cannot be bonded with traditional solders. Indium's unique cold welding properties allow it to produce a bond in a variety of non-metal applications.
8).Reduce or Eliminate the Use of Lead and Mercury: The use of indium in most of today's alkaline dry cell batteries allows them to be more environmentally friendly by eliminating mercury and by delivering more energy per battery. In the soldering arena, indium-containing alloys are candidates for replacing lead-bearing alloys.
9).Transparent Electrical Conductor: When indium (in the form of indium-tin oxide) is coated onto various materials such as glass or plastic films, it acts as a transparent electrical conductor and an infrared reflector. When architectural or photovoltaic glass is coated with indium-tin oxide (ITO) it keeps the harmful infrared rays of the sun from passing through. When coated onto automotive or aircraft windshields, it allows the glass to be electrically deiced or demisted as well as reducing the air conditioning requirement by reducing heat gain.
10).Malleable: Because indium is so soft and pliable (malleable), it can easily fill voids between two surfaces, even at cryogenic temperatures.
PHYSICAL PROPERTIES OF PURE INDIUM
CRYSTALINE STRUCTURE
Face-Centered Tetragonal: at
25C, a = 0.32525nm and c = 0.49465nm
MASS
Atomic weight
114.82
Specific gravity:
C
gm/cc
20
7.3
164
7.026
300
6.916
THERMAL PROPERTIES
Melting Point
156.6oC
Boiling point
2080oC
Coefficient of thermal
expansion
Linear, 24.8µm/m·K at
20 oC
Specific Heat:
C
J/kg·K
25
233
127
252
156.63(solid)
264
156.63(liquid)
257
Latent heat of fusion
28.47 kJ/kg
Latent heat of vaporisation
1959.42 kJ/kg
Thermal conductivity
83.7 W/m·K at 0 oC
Vapour pressure:
C
kPa
1215
0.1013
1421
1.013
1693
10.13
2080
101.3
ELECTRICAL PROPERTIES
Resistance:
C
nW-m
3.38 K ---- Super Conducting
20
84
154
291
181
301
280
348
Electrochemical equivalent
Valence 3, 396.4 µg/C
Electrode potential
InDeg/--> In3+ +
3e, 0.38V
MAGNETIC PROPERTIES
Magnetic susceptibility
Volumetric: 7.0 x 10-6mks
NUCLEAR PROPERTIES
Stable isotopes
113, 115
Thermal neutron cross
section. For 2.2 km/s neutrons:
absorption, 190 ± 10b;
scattering, 2.2 ± 0.5b
MECHANICAL PROPERTIES
Tensile strength.
K
MPa
295
1.6
76
15
4
31.9
Compressive strength
2.14 MPa
Hardness
0.9 HB
Elastic modulus at 20o C
12.74 GPa in tension
Poisson's ratio at 20oC
0.4498